| Bowler | Match | Venue | Season |
|---|---|---|---|
| H Hay | South Australia v Lord Hawke's XI | Unley, Adelaide | 1902-03 |
| HA Sedgwick | Yorkshire v Worcestershire | Hull | 1906 |
| WE Benskin | Leicestershire v Essex | Southend | 1906 |
| R Wooster | Northamptonshire v Dublin University | Northampton | 1925 |
| JC Treanor | New South Wales v Queensland | Brisbane | 1954-55 |
| VB Ranjane | Maharashtra v Saurashtra | Pune | 1956-57 |
| Arshad Khan | Dacca University v East Pakistan | Dhaka | 1957-58 |
| N Fredrick | Ceylon v Madras | Colombo | 1963-64 |
| JS Rao | Services v Jammu and Kashmir | New Delhi | 1963-64 |
| Mehboodullah | Uttar Pradesh v Madhya Pradesh | Lucknow | 1971-72 |
| RO Estwick | Barbados v Guyana | Bridgetown | 1982-83 |
| SA Ankola | Maharashtra v Gujarat | Pune | 1988-89 |
| J Srinath | Karnataka v Hyderabad | Secunderabad | 1989-90 |
| SP Mukherjee | Bengal v Hyderabad | Secunderabad | 1989-90 |
| SM Harwood | Victoria v Tasmania | Melbourne | 2002-03 |
| P Connell | Ireland v Netherlands | Rotterdam | 2008 |
| A Mithun | Uttar Pradesh v Karnataka | Meerut | 2009-10 |
Notes:
1) RR Phillips (Border) took a hat-trick in his first over in first-class cricket (v Eastern Province at Port Elizabeth, 1939-40) having previously played in four matches without bowling.
2) Rao, six days later, performed two hat-tricks in one match against North Punjab. Shortly afterwards, he was injured in a parachuting accident becoming a paraplegic.